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Cement milling and gypsum dehydration Because the cement gets hot due to the heat generated by grinding, gypsum can be partly dehydrated, forming hemihydrate, or plaster of Paris - 2CaSO 4 .H 2 O. On further heating, hemihydrate dehydrates further to a form of calcium sulfate known as soluble anhydrite (~CaSO 4 ).

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During the cement manufacturing process, upon the cooling of clinker, a small amount of gypsum is introduced during the final grinding process.Gypsum is added to control the "setting of cement". If not added, the cement will set immediately after mixing of water leaving no time for concrete placing.

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